There is no GUI or command line to perform this task. Microsoft recommends resetting the passwords that are cached at the hub site. The old passwords will still be authenticated at the local site, but will not be able to access network resources. Once replication occurs, the password is set to null until the user successfully logs in with the new password.
Reference:
http://technet.microsoft.com/en-us/library/cc730883.aspx
Reference:
http://technet.microsoft.com/en-us/library/cc730883.aspx
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